学術変革領域研究　2.5次元物質科学


学術変革領域研究　2.5次元物質科学

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研究成果

謝辞の記載についてAcknowledgement remarks

雑誌論文Papers

  1. N. Mazzucca, B. M. Kousa, K. Watanabe, T. Taniguchi, A. H. MacDonald, M. W. Bockrath
    Half-Integer Quantum Hall States in Two-Dimensional Graphite
    Phys. Rev. Lett. , 134 , 176302 (2025)
    DOI: 10.1103/PhysRevLett.134.176302
       
  2. K. Kaibara, Y. Yakiyama, M. Maruyama, Y. Gao, S. Okada, H. Sakurai
    Bandgap engineering of graphene by molecular conformation of trioxosumanene
    Jpn. J. Appl. Phys. , 64 , 075002 (2025)
    DOI: 10.35848/1347-4065/ade64c
         
  3. Y. Yakiyama, M. Li, D. Zhou, T. Abe, C. Sato, K. Sambe, T. Akutagawa, T. Matsumura, N. Matubayasi, H. Sakurai
    Biased Bowl-Direction of Monofluorosumanene in the Solid State
    J. Am. Chem. Soc. , 146 , 5224-5231 (2024)
    DOI: 10.1021/jacs.3c11311
    プレスリリース: https://resou.osaka-u.ac.jp/ja/research/2024/20240227_1
       
  4. J. Ażgin, M. Wesoły, K. Durka, H. Sakurai, W. Wróblewski, A. Kasprzak
    Expanding the library of sumanene molecular receptors for caesium-selective potentiometric sensors
    Dalton Trans. , 53 , 2964-2972 (2024)
    DOI: 10.1039/d3dt03885h
       
  5. A. Kasprzak, A. Zuchowska, P. Romanczuk, A. Kowalczyk, I. Grudzinski, A. Malkowska, A. Nowicka, H. Sakurai
    Oxidation-derived anticancer potential of sumanene-ferrocene conjugates
    Dalton Trans , 53 , 56-64 (2024)
    DOI: 10.1039/d3dt03810f
       
  6. H. Mizuno, H. Nakazawa, M. Harada, Y. Yakiyama, H. Sakurai, G. Fukuhara
    Sumanene-Stacked Supramolecular Polymers. Dynamic, Solvation-Directed Control
    Chem. Commun. , 59 , 9595-9598 (2023)
    DOI: 10.1039/D3CC02990E
       
  7. A. Kasprzak, M. Matczuk, H. Sakurai
    A sumanene-containing magnetic nanoadsorbent for the simple and effective removel of caesium salts from aqueous solutions
    Chem. Commun. , 59 , 9591-9594 (2023)
    DOI: 10.1039/D3CC02657D
       
  8. Y. Yakiyama, M. Li, H. Sakurai
    Fluorosumanenes as building blocks for organic crystalline dielectrics
    Pure Appl. Chem. , 95 , 421-430 (2023)
    DOI: 10.1515/pac-2023-0211
       
  9. Y. Shoji, R. Komiyama, M. Kobayashi, A. Kosaka, T Kajitani, R. Haruki, R. Kumai, S.-i Adachi, T Tada, N. Karasawa, H. Nakamura, H. Sakurai, T. Fukushima
    Collective bending motion of a two-dimensionally correlated bowl-stacked columnar liquid crystalline assembly under a shear force
    Science Adv. , 9 , 999 , eadg8202 (2023)
    DOI: 10.1126/sciadv.adg8202
       
  10. J. Han, Y. Uetake, Y. Yakiyama, H. Sakurai
    Derivatization of sumanenetrione through Lewis acid-mediated Suzuki-Miyaura coupling and an unprecedented ring opening
    Chem. Commun. , 59 , 4632-4635 (2023)
    DOI: 10.1039/D3CC00394A
       
  11. A. Kasprzak, A. G. -Walczak, A. Kowalczyk, B. Wagner, A. M. Nowicka, M. Nishimoto, M. K. Stawińska, H. Sakurai
    Application of Monoferrocenylsumanenes Derived from Sonogashira Cross-Coupling or Click Chemistry Reactions in Highly Sensitive and Selective Cesium Cation Electrochemical Sensors
    J. Org. Chem. , 88 , 4199-4208 (2023)
    DOI: 10.1021/acs.joc.2c02767
       
  12. J. S. Cyniak, Ł. Kocobolska, N. Bojdecka, A. G. -Walczak, A. Kowalczyk, B. Wagner, A. Nowicka, H. Sakurai, A. Kasprzak
    Synthesis of π-extended and bowl-shaped sumanene–ferrocene conjugates and their application in highly selective and sensitive cesium cations electrochemical sensors
    Dalton Trans. , 52 , 3137-3147 (2023)
    DOI: 10.1039/D3DT00084B
       
  13. M. Nishimoto, Y. Uetake, Y. Yakiyama, A. Saeki, J. Freudenberg, U. H. F. Bunz, H. Sakurai
    Acceleration Effect of Bowl-Shaped Structure in Aerobic Oxidation Reaction: Synthesis of Homosumanene ortho-Quinone and Azaacene-Fused Homosumanenes
    Chem. Eur. J. , 29 , e202203461 (2022)
    DOI: 10.1002/chem.202203461
       
  14. H. Nakazawa, Y. Uetake, Y. Yakiyama, H. Sakurai
    Pentagon-Fused Sumanenes on the Aromatic Peripheries en Route to the Bottom-Up Synthesis of Fullerenes
    Synlett , 34 , 374-378 (2023)
    DOI: 10.1055/a-1992-0487
       
  15. M. Nishimoto, Y. Uetake, Y. Yakiyama, H. Sakurai
    Thermodynamic Differentiation of the Two Sides of Azabuckybowl through Complexation with Square Planar Platinum(II)
    Chem. Asian J. , 18 , e202201103 (2022)
    DOI: 10.1002/asia.202201103
       
  16. H. Nakazawa, Y. Uetake, Y. Yakiyama, H. Sakurai
    Synthesis of Fully Substituted Sumanenes at the Aromatic Periphery through Hexabromomethylation
    Asian J. Org. Chem. , 12 , e202200585 (2022)
    DOI: 10.1002/ajoc.202200585
       
  17. J. Han, Y. Yakiyama, Y. Takeda, H. Sakurai
    Sumanene-Functionalised Bis(terpyridine)-Ruthenium(II) Complexes Showing Photoinduced Structural Change and Cation Sensing
    Inorg. Chem. Front , 10 , 211–217 (2022)
    DOI: 10.1039/D2QI01801B
       
  18. H. Nakazawa, A. Ohya, Y. Morimoto, Y. Uetake, N. Ikuma, K. Okada, M. Nakano, Y. Yakiyama, H. Sakurai
    Synthesis of Sumanene-fused Acenes
    Asian J. Org. Chem. , 11 , e202200471 (2022)
    DOI: 10.1002/ajoc.202200471
       
  19. I. Weber, M. Tsuge, P. Sundararajan, M. Baba. H. Sakurai, Y. -P. Lee
    Infrared and Laser-Induced Fluorescence Spectra of Sumanene Isolated in Solid para-Hydrogen
    J. Phys. Chem. A , 126 , 5283-5293 (2022)
    DOI: 10.1021/acs.jpca.2c02906
       
  20. M. Li, X. Chen, Y. Yakiyama, J. Wu, T. Akutagawa, H. Sakurai
    Turning Dielectric Response by Co-crystallisation of Sumanene and Its Fluorinated Derivative
    Chem. Commun. , 58 , 000 , 8950-8953 (2022)
    DOI: 10.1039/D2CC02766F
       
  21. M. Li, J.-Y. Wu, K. Sambe, Y. Yakiyama, T. Akutagawa, T. Kajitani, T. Fukushima, K. Matsuda, H. Sakurai
    Dielectric Response of Difluorinated Sumanene Caused by an In-plane Motion
    Mater. Chem. Front. , 6 , 1752–1758. (2022)
    DOI: 10.1039/D2QM00134A
           
  22. M. Nishimoto, Y. Uetake, Y. Yakiyama, F. Ishiwari, A. Saeki, H. Sakurai
    Synthesis of the C70 Fragment Buckybowl, Homosumanene, and Heterahomosumanenes via Ring-Expansion Reactions from Sumanenone
    J. Org. Chem. , 87 , 2508-2519 (2022)
    DOI: 10.1021/acs.joc.1c02416
       
  23. A. Kasprzak, A. Tobolska, H. Sakurai, W. Wróblewski
    Tuning the sumanene receptor structure towards the development of potentiometric sensors
    Dalton Trans. , 51 , 468-472 (2021)
    DOI: 10.1039/d1dt03467g
       

書籍Books

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学会発表Presentations, Lectures

  1. H. Ago
    Synthesis and Device Applications 2.5D Materials: Beyond 2D Materials with New Degrees of Freedom
    22nd International Workshop on Junction Technology (IWJT2025), ( 2025 , 6 )
       
  2. H. Sakurai
    Recent Progress in Sumanene Chemistry
    International Symposium for the 80th Anniversary of the Tohoku Branch of the Chemical Society of Japan, ( 2023 , 9 )
       
  3. 櫻井英博
    Sumanene: A C3v-symmetric Fragment of C60
    第65回フラーレン・ナノチューブ・グラフェン総合シンポジウム, ( 2023 , 9 )
       
  4. H. Sakurai
    Buckybowl Chemistry: Interplay of Experiments and Theory
    Pure and Applied Chemistry International Conference, ( 2023 , 1 )
       
  5. 櫻井英博
    スマネン合成から２０年
    第83回有機合成化学協会関東支部シンポジウム, ( 2022 , 11 )
       
  6. H. Sakurai
    Fullerenol as a Unique, Non-coordinative Matrix for Colloidal Metal Nanoparticles
    The 4th International Symposium on the Synthesis and Application of Curved Organic pi-Molecules and Materials, ( 2022 , 9 )
       
  7. H. Sakurai
    Sumanenyl Cations as Redox-active Buckybowls
    241st ECS Meeting, ( 2022 , 6 )
       
  8. H. Sakurai
    Recent Progress in Sumanene Chemistry
    Symposium on Organic and Applied Chemistry, ( 2021 , 12 )